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    • 专利摘要:
    Method for preparing beer concentrate, comprising the following steps: A) subjecting beer or cider (1) to a first concentration step to obtain a retentate (2) and a permeate (3) comprising alcohol (3a) and volatile flavor components (3b), B) subjecting the permeate (3) to an adsorption unit wherein the volatile flavor and alcohol-containing permeate is passed over or through an adsorption unit, C) recovering one or more of the flavor components (3b) from the adsorption unit in a further recovery process D) combining the retentate (2) with the flavor components (3b)
    公开号:BE1025834B1
    申请号:E2018/5027
    申请日:2018-01-18
    公开日:2019-08-14
    发明作者:Schutter David De；Pierre Adam；Miguel Monsanto；Andre Joao
    申请人:Anheuser-Busch Inbev S.A.；
    IPC主号:
    专利说明:

    Process for the production of a beer or cider concentrate
    Technical area
    The present invention relates to a method for preparing beer or cider concentrate consisting of alcohol and flavor components, and beer or cider prepared therewith, respectively. More specifically, the invention relates to a multi-step concentration method, wherein the first step comprises a concentration step that results in a concentrated retentate and an aqueous permeate fraction comprising alcohol and volatile flavor components, and wherein the volatile flavor and alcohol-containing permeate over or through a adsorption unit.
    BACKGROUND OF THE INVENTION
    In recent years, home distribution devices for domestic use, where multiple beverage components or beverages are added together so that customers can create their own compositions adapted to their own taste at home, have become very popular. This trend also applies to fermented drinks, such as malt-based fermented drinks, such as beers of various tastes and types.
    Another way, on the one hand, to reduce the packaging costs per unit volume of beer and, on the other hand, to offer customers a large range of choice, is to provide containers filled with beer concentrates that can only
    BE2018 / 5027 are used or mixed with each other and diluted with a liquid diluent. The containers may be in the form of containers as such or as unit doses such as a capsule or a pad. By mixing such beer concentrates with a liquid diluent, a desired beverage can be created in situ and subsequently or simultaneously served. The addition and mixing of the liquid diluent with the unit dose is generally performed in a dispenser.
    The underlying problem of producing the final beer drink starting with a beer concentrate is to meet as far as possible the specifications assigned to regular, non-reconstituted beers, such as bottled beers, canned beers and especially draft beers. This problem poses major challenges, especially with regard to the level of taste acceptability by the consumer, such as distinctive aroma, taste and mouthfeel, due to the fact that most concentration procedures lead to a reduction in many taste or aroma components.
    The aroma (taste and odor) of beer is determined by taste substances derived from raw materials (malt, hops) as well as taste substances that are formed during the brewing process, mainly during heat treatments (mashing, boiling wort) and fermentation. Beer contains a large number of different flavor substances, including volatile and non-volatile components. Important beer flavor substances include hydrophobic as well as hydrophilic compounds. The relative concentration levels in which these flavor substances
    BE2018 / 5027 present in a beer determine the taste character or flavor profile of the beer. An important challenge for every brewer is to ensure a constant taste quality.
    Because the quality and composition of the natural raw materials used in brewing beer have a tendency to vary, it is evident that the flavor formation pathways responsible for the formation of flavor substances during brewing are influenced by many different factors. maintaining a constant beer flavor quality is indeed a very difficult task. The taste profile of beer is highly dependent on the concentration levels of certain volatile beer flavor substances that are formed during fermentation. Typical examples of such beer flavor substances include: Diacetyl (butane-2,3-dione); acetaldehyde; dimethyl sulfide; ethyl acetate; isoamyl acetate (3-methyl
    1-butyl acetate); ethyl valerate (ethyl pentanoate); ethyl hexanoate; isoamyl alcohols (3-methylbutan-1-ol);
    2-methylbutan-1-ol.
    In particular, beer is a very challenging drink to make concentrate because, unlike drinks produced from fruit juice fermentation such as wine-like products, the aromas in beer are more subtle and less concentrated, reducing the loss of only a small portion will have a major effect on the organoleptic observation of the final rehydrated product during the concentration step. In addition, the
    BE2018 / 5027 reconstituted beverage, thanks to the wide popularity of the beverage and the wide audience of demanding beer lovers, expects it to meet expectations with regard to its characteristic odor, taste, mouthfeel, foam properties, color, and even turbidity perception. Reconstituted beer simply cannot taste like diluted beer that lacks certain characteristics; for customer acceptance, it must contain the qualities of truly unprocessed beer.
    Methods for producing beer concentrates and rehydrating them into final drinks are known in the art.
    Various methods for concentrating alcoholic beverages known in the brewing industry include processes such as freeze drying, reverse osmosis, and filtration. The present invention provides a method for producing high-density, naturally alcohol-enriched beer concentrate, the method providing an advantageous concentration factor of at least 5, 10, 15, to 20 or more, while at the same time ensuring high and selective preservation of flavor components of natural beer, including volatile components.
    These and other advantages of the present invention are discussed further.
    Summary of the invention
    The present invention is defined in the appended independent claims.
    Preferred embodiments are defined in the dependent claims. In particular, the present invention is directed to a method of
    BE2018 / 5027 preparation of beer concentrate, comprising the steps of:
    A) subjecting beer or cider (1) to a first concentration step to obtain a retentate (2) and a permeate (3) comprising alcohol (3a) and volatile flavor components (3b),
    B) subjecting the permeate (3) to an adsorption step in which the volatile flavor and alcohol-containing permeate is passed over or through an adsorption unit,
    C) recovering the flavor components (3b) from the adsorption unit in a further recovery process
    D) combining the retentate (2) with the flavor components (3b)
    In particular, the present invention relates to a method for preparing beer concentrate, which comprises the steps of:
    (a) subjecting beer or cider (1) to a first concentration step comprising reverse osmosis and / or microfiltration and / or nanofiltration and / or ultrafiltration (A) to produce a retentate (2) and a fraction comprising alcohol and volatile flavor components (3) ), wherein the retentate (2) is characterized by the concentration of non-filterable compounds equal to or higher than 20% (w / w), preferably 30% (w / w), most preferably 40% ( w / w), as calculated by density measurement corrected for the alcohol content;
    (b) subjecting the permeate (3) to an adsorption step in which the volatile flavors
    BE2018 / 5027 alcohol-containing permeate is passed over or through an adsorption unit, (c) recovering the flavor components (3b) from the adsorption unit in a further recovery process (d) combining the retentate (2) with the flavor components ( 3b)
    The concentrated volatile flavor fractions can be added to the retentate independently of each other, or used as an ingredient in beer or cider, as a component of beer or cider reconstitution, or added as a flavor component to beer or cider. Brief description of the figures
    For a detailed understanding of the nature of the present invention, reference is made to the following detailed description in combination with the accompanying drawings, wherein:
    Figure 1 shows a block diagram with the most important steps of the method according to the present invention. A - first concentration step B second concentration step comprising the adsorption unit; C desorption step
    - beer subjected to microfiltration / nanofiltration / ultrafiltration / reverse osmosis; 2 - retentate; 3 - permeate comprising ethanol 3a) and volatile aroma components 3b; 4 - concentrated beer or cider
    Figure 2 shows a block diagram with the most important steps of a method of another embodiment according to the present invention. A first concentration step; B - second concentration step
    BE2018 / 5027 comprising adsorption unit; C 'fractionation step, preferably distillation C - desorption step
    - beer subjected to microfiltration / nanofiltration / ultrafiltration / reverse osmosis 2 - retentate; 3-permeate comprising ethanol
    3a) and volatile aroma components 3b; 4 - concentrated beer or cider
    Figure 3 shows a graph showing the relationship between the concentration factors of different retentates (4) obtained from different beers (beer 1-4), and the number of non-filterable compounds (% solids) obtained in said retentates after the first concentration step and retentate concentration step (RC), according to the method of the invention.
    Definitions
    As used herein, the term concentrate as defined in the Oxford dictionary means: A substance made by removing or reducing the diluent; a concentrated form of something (cf.
    http: // www. oxforddictionaries. com / definition / english / concentrate). In line with this, the term beer or cider concentrate or, alternatively (concentrated) beer or cider base or beer or cider syrup, refers to beer or cider, respectively, from which the majority of its solvent component - ie water - was removed while the Most of the dissolved components with properties such as taste, odor, color, mouthfeel etc. are retained.
    BE2018 / 5027
    As used herein, the term beer should be interpreted according to a rather broad definition:
    wort, the drink obtained by fermentation from raw materials prepared with starch or sugary ingredients, including hop powder or hop extracts and potable water. In addition to barley malt and wheat malt, only the following should be taken into account for brewing, mixed with, for example, wheat malt, starch or sugar-containing raw materials in which the total amount may not exceed 80%, preferably 40% of the total weight of the starch or sugar-containing raw materials:
    (a) maize, rice, sugar, wheat, barley and its various forms.
    (b) sucrose, converted sugar, dextrose and glucose syrup.
    Although not all fermented malt-based beverages can be called beer according to certain national laws, in the context of the present invention, the terms beer and fermented malt-based beverage are used herein as synonyms and are interchangeable. Therefore, as used herein, the terms reconstituted beer and reconstituted fermented malt-based beverage are to be interpreted as beverages that are substantially identical in composition to beer but are obtained by the addition of the solvent, i.e., water or
    BE2018 / 5027 carbonated water, to a previously prepared beer concentrate.
    Then, as used herein, the term cider is to be interpreted as any alcoholic beverage resulting from the fermentation of apple juice or apple juice mixed with max. 10% pear juice. This term also includes any product of this fermented apple juice that has been further modified by adding such standard cider production additives such as acids (lemon or tartar) and / or sugar, filtering, cooling, saturation with carbon dioxide, pasteurization, etc., which has been commercialized under the term cider.
    Furthermore, as used herein, the term volatile flavor components is to be understood as any of the substances contained in beer that contribute to its complex olfactory profile, said substances having a chemical character with a boiling point lower than that of water. Examples of volatile beer flavor components include, but are not limited to, acetaldehyde, N-propanol, ethyl acetate, isobutanol, isoamyl alcohol, isoamyl acetate, ethyl hexanoate, ethyl octanoate.
    As used herein, the term non-filterable compounds should be interpreted as referring to all different compounds included in any type of beer or cider that cannot pass through a nanofiltration membrane, ie beer compounds with a size greater than 150 Da, 180 Da, or 200 Da, which the cut-off of the
    BE2018 / 5027 molecular weight retention size depends on a particular nanofiltration membrane. In contrast
    to filterable connections, surrounding water, monovalent and sometimes bivalent ions, low molecular weight alcoholssuch as ethanol, low molecular weight esters and a number fleeting taste components, include the non-filterable connections me t namesugars, mostly
    polysaccharides; sugar alcohols, polyphenols, pentosans, peptides and proteins, high-molecular alcohols, high-molecular weight esters, partially polyvalent ions, and many other particularly organic and very different compounds that depend on the type of beer or cider. Due to the complexity and differences between the different beer or cider compositions, the combined concentration of the non-filterable compounds is often referred to as the concentration of sugars or concentration of solids (in great simplification and without being exact) and can be calculated automatically from the mass balance, taking into account parameters such as density, viscosity, rheology, original similar weight or extract, actual similar weight or extract, degree of fermentation (RDF) and / or alcohol content. In the brewery, the concentration of non-filterable compounds is routinely determined from the density measurements (actual extract), corrected for the density of the measured amount of ethanol, with ethanol being the most
    BE2018 / 5027 is a common compound with a density of <1 g / cm 3, so that it most significantly influences the density measurement. Such measurements are well known in the art and are routinely performed by standard beer analysis systems such as the Anton Paar Alcoholyzer apparatus, and can therefore be easily and simply performed by an expert in brewing beer.
    The amount of components dissolved in beer can also be expressed in similar weight (relative density) or apparent specific weight. The first method measures the density (volume weight) of beer, divided by the density of water as a reference substance; in the second method, the density is measured as the weight of a volume of beer relative to the weight of an equal volume of water. For example, a specific gravity of 1,050 (50 points) means that the solution is 5% heavier than an equal volume of water. The densities of water, and therefore also beer, vary with temperature; therefore, for both the specific gravity and the apparent specific gravity, the measurement of the sample and the reference value is performed under the same specific temperature and pressure conditions. Pressure is almost always 1 atm, equivalent to 101.325 kPa, while the temperatures may differ depending on the choice of additional systems for measuring beer density. Examples of such systems
    BE2018 / 5027 are two empirical scales: Plato and Brix, and are often used in the brewery and wine industries respectively. Both scales represent the strength of the solution as a percentage of sugar per mass; one degree of Plato (abbreviated ° P) or one degree of Brix (symbol ° Bx) is 1 gram of sucrose in 100 grams of water. In particular, there is a difference between these units in that both trays have been developed for sucrose solutions of different temperatures, but this is so insignificant that both can be used interchangeably. For example, beer measured at 12 ° Plato at 15.5 ° C has the same density as a water-sucrose solution containing 12% sucrose at 15.5 ° C, which is approximately the same as 12 ° Brix, with the same density as a water sucrose solution of 12% per mass at 20 ° C. The Plato and Brix trays have a specific weight advantage in that they represent the density measurement of the amount of fermentable materials, which is particularly useful in the first stages of the brewing process. Because, of course, both beer and wort are composed of more solids than sucrose, this is not precise. The ratio between degrees Plato and specific gravity is not linear, but a good approximation is that 1 ° P equals 4 brewer points (4 x 0.001); so 12 ° Plato corresponds to a specific weight of 1,048 [1+ (12 x 4 x 0.001)].
    BE2018 / 5027
    The term original specific weight or original extract refers to the specific weight as measured before fermentation, while the term final specific weight or final extract refers to the specific weight as measured after completion of fermentation. Generally, specific gravity refers to the specific specific gravity of the beer at different stages in the fermentation. Initially, for the production of alcohol through the fermentation, the specific gravity of wort (i.e. the ground malt for fermenting the beer) is particularly dependent on the amount of sucrose. Therefore, the measurement of the original specific gravity at the beginning of the fermentation can be used to determine the sugar content in Platoof Brix dishes. As fermentation proceeds, the yeast converts sugars and carbon dioxide, ethanol, yeast biomass and flavor components. The reduction of the sugar content and the increasing amount of ethanol, which has considerably less density than water, leads to a reduction in the specific gravity of the fermenting beer. The measurement of the original specific gravity as compared to the final specific gravity can be used to estimate the amount of converted sugar and thus the amount of ethanol produced. For example, for standard beer, the original specific gravity can be 1,050 and the final
    BE2018 / 5027 specific weight 1.010. Also, the knowledge of the original specific gravity of a drink and its alcohol content can be used to estimate the number of sugars that have been converted during fermentation. The extent to which sugar is fermented in alcohol is expressed by the term actual fermentation rate or RDF, and is often mentioned as a fraction of the specific gravity converted to ethanol and CO 2 . The RDF of beer is in theory an indication of the sweetness because beers often have more residual sugar and therefore a lower RDF.
    Concentration steps may include a variety of techniques recognized in the art that allow for partial or substantial separation of water from the beer, thus leading to retention of most of the components dissolved herein in a lower than original volume. Many techniques currently used in the beverage industry rely on so-called membrane technologies that offer a cheaper alternative to conventional heat treatment processes and involve separating substances into two fractions using a semi-permeable membrane. The fraction comprising particles that are smaller than the pore size of the membrane can pass through the membrane and, as used herein, is referred to as permeate or filtrate. Everything that remains on the input side of the membrane is referred to herein as retentate.
    BE2018 / 5027
    Typical membrane filtration systems include, for example, pressure-driven microfiltration, ultrafiltration, nanofiltration, and reverse osmosis techniques. As used herein, the term microfiltration refers to a membrane filtration technique for retaining particles with a size of 0.1 to 10 μm and larger. Microfiltration is normally a low pressure process, typically operating at a pressure in the range of 0.34 - 3 bar 1 . Microfiltration allows separation of particles such as yeast, protozoa, large bacteria, organic and inorganic deposits, etc. Next, the term ultrafiltration, as used herein, refers to a membrane filtration technique for retaining particles with a size of 0.01 μm or larger. Ultrafiltration normally retains particles with a molecular weight greater than 1000 daltons, such as most viruses, proteins of certain sizes, nucleic acids, dextrins, pentosan chains, etc. Normal operating pressure for ultrafiltration is between 0.48 and 10 bar. Also, as used herein, the term nanofiltration means a membrane filtration technique for retaining particles with a size of 0.001 μm to 0.01 μm and larger. Nanofiltration allows the retention of bivalent or polyvalent ions, such as bivalent salts, and most organic components greater than about 180 daltons, including oligosaccharides and many
    Where the unit bar is 100,000 Pa according to the definition of IUPAC, [1 Pa = 1 N / m A 2 = 1 kg / m * s A 2 in S1 units.]
    BE2018 / 5027 flavor compounds while allowing water, ethanol monovalent ions and some organic molecules such as many aromatic esters to pass through. A working pressure of 8-41 bar is characteristic of nanofiltration. Where nanofiltration occurs under inlet pressure in the upper end of this range, ie from 18 bar, it will be referred to as high pressure nanofiltration as used herein. Finally, as used herein, the term reverse osmosis is to be interpreted as referring to a high pressure membrane process where the applied pressure is used to surpass osmotic pressure. Reverse osmosis usually permits the retention of particles with a size of 0.00005 μm to 0.0001 μm and larger, i.e. almost all particles and ionic species. Substances with a molecular weight higher than 50 Dalton are almost all retained without exception. The operating pressure is typically between 21 and 7 6 bar, but can go up to 150 bar in special applications.
    Furthermore, as described herein, the term volatile flavor components is to be understood as any of the substances present in beer that contribute to its complex olfactory profile, wherein said substances by their chemical nature have a boiling point lower than that of water.
    Examples of volatile beer flavor components include, but are not limited to, acetaldehyde, N-propanol, are non-ethyl acetate, isobutanol, isoamyl alcohol, isoamyl acetate, ethyl hexanoate, ethyl octanoate, and many others.
    BE2018 / 5027
    Detailed description of the invention
    The present invention is directed to a method for preparing beer concentrate, comprising the steps of A) subjecting beer or cider (1) to a first concentration step to obtain a retentate (2) and a permeate (3) comprising alcohol (3a) and volatile flavor components (3b), B) subjecting the permeate (3) to an adsorption step in which the volatile flavor and alcohol-containing permeate is passed over or through an adsorption unit, C) recovering the flavor components (3b) from the adsorption unit in a further recovery process D) combining the retentate (2) with the flavor components (3b).
    In a preferred embodiment, the present invention is directed to a method for preparing beer concentrate, which comprises the steps of:
    A) subjecting beer or cider (1) to a first concentration step comprising reverse osmosis and / or microfiltration and / or nanofiltration and / or ultrafiltration to obtain a retentate (2) and a permeate (3) comprising alcohol (3a) and volatile flavor components (3b),
    B) subjecting the permeate (3) to an adsorption step in which the volatile flavor and alcohol-containing permeate is passed over or through an adsorption unit,
    C) recovering the flavor components (3b) from the adsorption unit in a further recovery process
    BE2018 / 5027
    D) combining the retentate (2) with the flavor components (3b)
    According to a further embodiment, the further recovery process comprises washing out the adsorbed volatile flavor components in a volume of water or alcohol to obtain a concentrated fraction of volatile flavor components.
    A preferred embodiment of the method according to the present invention is the method wherein the further recovery process comprises washing out the adsorbed volatile flavor components in a volume of alcohol to obtain a concentrated fraction of volatile flavor components with the alcohol from a distillation step of the alcohol
    The adsorbent, or its composition, is selected based on the flavorings to be adsorbed.
    Preferred flavor components are selected from acetaldehyde, Npropanol, ethyl acetate, isobutanol, isoamyl alcohol, isoamyl acetate, ethyl hexanoate, ethyl octanoate. In a preferred process, the adsorption unit comprises a plurality of serial or parallel adsorption units, each unit having a specific high affinity for specific flavor components.
    Preferred first concentration steps according to the method of the present invention are those characterized by the concentration of non-filterable compounds equal to or higher than preferably 30% (w / w), most preferably 40% (w / w), as calculated by density measurement corrected for the alcohol content.
    BE2018 / 5027
    When beer (1) is subjected to reverse osmosis (A) according to the invention, clear beer is preferably used which has been treated with any ordinary beer clearance technique to remove yeast and must from the other particles with a diameter greater than 0.2 μm. Such techniques are conventional and known in the art of beer preparation. For example, these include centrifugation, filtration through, for example, kieselguhr (diatomaceous earth), optionally preceded by centrifugation, or other conventional microfiltration techniques.
    As can be understood from the present description, the method of the invention is particularly advantageous for obtaining low-volume beer or cider concentrate with a high density with limited or ideally no loss of volatile flavor components. The concentration of the end product largely depends on the degree of concentration of the retentate. According to the present invention, the present invention provides a method wherein the retentate not only comprises a majority of beer (or cider) flavor components, but may optionally also be characterized by a high concentration factor of 5, 10, 15 or even 20 or more.
    As used herein, the term concentration factor is to be understood as the ratio of the beer or cider volume that is subjected to step A) to the volume of the retentate obtained at the end of step A), ie the ratio of the feed volume to the volume of the volume of the retentate obtained in step A) of the process of the
    BE2018 / 5027 the present invention. In a particularly preferred embodiment, a method according to the previous embodiments is provided, wherein the retentate obtained from step A) is characterized by a concentration factor of 5 or higher, preferably 10 or higher, more preferably 15 or higher, and most preferably of 20 or higher. A ratio between the concentration factor in the sense defined above and the concentration of non-filterable compounds that may possibly be obtained in the retentate of step A) naturally depends on the type of beer or cider that was initially subjected to nanofiltration or reverse osmosis, that has been demonstrated and can be deduced from the graph presented in
    Figure 3, where each line represents a different drink (lines
    1-4 were obtained for different beers, rule obtained for cider)
    In the case of cross-flow filtration, we can always obtain the concentration in one pass. But to make the operation more economical, a multi-phase operation is performed.
    In accordance with the above, the present invention is based on the finding that concentrating beer in a first concentration step followed by an adsorption step on the permeate allows a high concentration factor while maintaining appropriate volatile flavor components.
    After the concentration step, the highly concentrated retentate (2) is collected while the aqueous permeate (3) is processed by adsorption
    BE2018 / 5027 unit to selectively obtain volatile flavor components and optionally ethanol.
    The permeate from the first concentration step can be subjected to fractionation, preferably distillation, for recycling back to the adsorption unit as a desorption step, allowing specific concentration processes for the recovery of the extract and the volatile aroma.
    Figure 1 schematically shows a diagram of the method according to the present invention in which a beer (1) is subjected to a first concentration step comprising, for example, ultrafiltration (semi-permeable membrane as a physical barrier to enable the transit of most beer components with an average molecular weight (MW)>
    concentrated extract of the beer and a permeate mainly comprising water and ethanol, but also an amount of volatile flavor components and an amount of extract. The permeate is then processed by the adsorption unit to recover extract and volatile flavor components that can be added to the retentate (2), or that can be used as an ingredient in beer or cider, as a beer or cider reconstitution component, or can be added as a flavor component to beer or cider.
    Figure 2 schematically shows a diagram of a method according to the present invention in which one is subjected to a first one
    BE2018 / 5027 concentration step comprising, for example, ultrafiltration (semi-permeable membrane as physical barrier to enable the transit of most beer components with an average molecular weight (MW)> 1000 Da) to obtain a retentate (2) including concentrated extract of the beer and a permeate (3) mainly comprising water and ethanol, but also an amount of volatile flavor components and an amount of extract. The permeate (3) is then processed by adsorption unit (B). The fractionation at 3 a), for example by distillation, allows obtaining a fraction comprising ethanol and volatile flavor components that can be recycled to the adsorption unit to resorb flavor components 3b to obtain a concentrated fraction of volatile flavor components (3b).
    The concentrated volatile flavor fraction (3b) can be added to the retentate independently of each other, or used as an ingredient in beer or cider, as a component beer or cider reconstitution, or added as a flavor component to beer or cider.
    The distillation mentioned above is a classic example of a fractionation technique that is particularly suitable for separating alcohol and volatile components from water. The term distillation, as used herein, refers to the separation of a liquid mixture into components thereof, utilizing the difference in relative volatility and / or boiling point of the components, by inducing the successive
    BE2018 / 5027 evaporation and condensation in a process of heating and cooling. Examples of distillation may include simple distillation, fractional distillation, multi-phase distillation, azeotropic distillation, and steam distillation.
    Distillation is part of a larger group of separation processes that are based on phase transition, collectively called fractionation. Other examples of fractionation include column chromatography based on the difference in affinity between the stationary phase and the mobile phase, and fractional crystallization and fractional freezing, both using the difference in crystallization and melting points of different components of a mixture at a given temperature.
    In an advantageous arrangement of the present invention, the method may include fractionation arrangement, preferably distillation, in which different fractions are analyzed for the presence of different components such as different volatile flavor components and then subsequently discarded selectively, which provides greater control over the flavor profile of the final beer concentrate of the invention.
    The flavor profile of the concentrated beer can be adjusted advantageously by selectively increasing the concentration levels of some of these flavor substances. This selective adsorption can be achieved in a very effective way
    BE2018 / 5027 obtained by contacting the permeate with an adsorption unit, for example one or more column-containing adsorbent, for example porous adsorbent particles that selectively adsorb one or more of said beer flavor substances, and then desorbing a portion of the adsorbed beer flavor substances from the adsorbent and re-adding this portion to the concentrated beer or other beer. This embodiment is particularly suitable for adjusting the concentration levels of beer flavor esters (ethyl acetate, ethyl hexanoate, ethyl valerate and isoamyl acetate). Furthermore, undesirable flavor deviations resulting from elevated levels of concentration of one or more of the aforementioned beer flavor substances can be efficiently corrected by selectively removing at least a portion of these flavor substances through high affinity adsorbents for these substances. This embodiment is particularly suitable for reducing the levels of diacetyl, acetaldehyde and / or dimethyl sulfide. The adsorbents used according to the present invention have an affinity for one or more of the aforementioned beer flavoring substances, thereby allowing the selective removal of at least one of these beer flavoring substances. In addition, the adsorbents typically have a low affinity for ethanol.
    Selective desorption of beer flavor substances adsorbed by the adsorbent
    BE2018 / 5027 is advantageously obtained by passing an eluent through the adsorber unit under conditions that promote desorption of a subset of beer flavor substances.
    Adsorbents with a high affinity for ethyl acetate, ethyl hexaonate, ethyl valerate and isoamyl acetate can thus, for example, be appropriately desorbed under conditions that promote desorption of ethyl hexanoate, ethyl valerate and isoamyl acetate. These flavor esters can therefore almost always be removed quantitatively and separated from the ethyl acetate.
    Re-adding these three flavor esters to the beer from which they were originally removed provides a beer with a reduced ethyl acetate content. The eluant used to desorb beer flavor substances is preferably selected from water, ethanol, mixtures of water and ethanol. In order to elicit the sequential release of different beer flavor substances, elution conditions can be changed during the desorption process. For example, the composition of the eluent can be changed, e.g., by varying the ethanol content. Consecutive release can also be achieved by changing the temperature conditions such as the temperature of the eluent and / or the design and configuration of the desorption unit.
    The transit route (s) of the adsorption unit of the present invention can be provided in any suitable form. This can be provided by the
    BE2018 / 5027 filling a column, container, vessel or tube with an adsorbent.
    In another preferred embodiment of a method of the present invention, the method comprises the step of column adsorption. Such column absorption includes the use of a column filled with, for example, an adsorbent resin. A column filled by gravity is a particularly suitable form of transit route. The column can be filled in any suitable manner with any suitable adsorbent arrangement. The ratio of the length of the column to its diameter is 4: 1 or greater. The adsorbent can be provided in any suitable form. A particularly suitable form for the adsorbent is in the form of beads which can be of any suitable shape and size.
    The adsorption / desorption step can also be carried out with multiple transit routes containing an adsorbent to which an eluent is added to a level that was calculated to ensure the tendency towards specific flavor components.
    In another preferred embodiment of a method of the present invention, the method comprises the step of column adsorption.
    Such column absorption includes the use of a column filled with, for example, an adsorbent resin.
    The volume percentage of alcohol can be adjusted before transit through the further transit routes. This is preferably done by removing alcohol from the combined alcohol / raw material extract in an evaporator. The fractions
    BE2018 / 5027 can be collected in any suitable way. Any suitable number of fractions can be collected. The set of fractions can be applied to maximize the concentration of a desired flavor component in a specific fraction. A single-line spectrophotometer can be used to detect the presence of specific flavor components in the eluent and indicate appropriate fractions. The concentration of alcohol in the eluent mixture can be increased in any suitable, substantially constant amount while the eluent contains the intended flavor components. The adsorption / desorption step can also be carried out with multiple transit routes containing an adsorbent to which an eluent is added to a level that was calculated to ensure the tendency towards specific flavor components.
    The present method can suitably use adsorbents made from different materials such as resin or a mixture of different resins. These adsorbent particles are preferably polymer-based, which means that the particles consist of polymer or that at least the surface of the particles consists of polymer. Examples of polymers that can be suitably used as an adsorbent include polystyrenes, polymethacrylates, blends, and copolymers thereof. Preferred adsorbents are made from cross-linked polystyrene, most preferably a styrene-divinylbenzene copolymer. Adsorbents that can be appropriately used
    BE2018 / 5027 is used, in particular for the selective removal of diacetyl, acetaldehyde and / or dimethyl sulfide, comprising adsorbents containing amine functionalities.
    Examples of such adsorbents include chitosan,
    Sevalamer ™ (copolymer of 2- (chloromethyl) oxirane (epichlorohydrin) and prop-2-and-1-amine) and
    Siliabond ™ amine-functionalized silica gels.
    In a preferred embodiment, the adsorbents have a high affinity constant as previously defined for one or more esters selected from ethyl acetate, isoamyl acetate, ethyl valerate and ethyl hexanoate, more preferably from one or more esters selected from isoamyl acetate, ethyl valerate and ethyl hexanoate, and most preferably for isoamyl acetate.
    A first concentration step according to the present invention, prior to an adsorption step, provides a more efficient adsorption in terms of yield and specific taste recovery, thereby preventing competitive adsorption, reducing loss of flavor components, more specifically for flavor components such as esters (e.g. ethyl acetate, isoamyl acetate) and higher alcohols (e.g., isoamyl alcohol, isobutanol). Other benefits associated with this are minimizing saturation of adsorbents; reduction in the cost of regeneration of adsorbents; increased service life of the adsorbents and reduction of the volume to be supplied to the adsorption step.
    权利要求:
    Claims (9)
    [1]
    CONCLUSIONS
    Method for preparing beer concentrate, comprising the following steps:
    A) submitting beer or cider (1) On a first concentration step for it to gain from a retentate ( 2) and a permeate ( 3) including alcohol ( 3a)
    and volatile flavor components (3b),
    B) subjecting the permeate (3) to an adsorption unit wherein the volatile flavor and alcohol-containing permeate is passed over or through an adsorption unit,
    C) recovering one or more of the flavor components (3b) from the adsorption unit in a further recovery process D) combining the retentate (2) with the flavor components (3b), the further recovery process including washing out the adsorbed volatile flavor components in a volume of alcohol to obtain a concentrated fraction of volatile flavor components with the alcohol from a distillation step of the alcohol (3a).
    [2]
    The method of claim 1, wherein said first concentration step comprises reverse osmosis and / or microfiltration and / or nanofiltration and / or ultrafiltration to obtain a retentate (2) and a permeate (3) comprising alcohol (3a) and volatile flavor components (3b)
    [3]
    Method according to claims 1 and 2, wherein the adsorption unit comprises one or more of a taste-adsorbent adsorbent
    BE2018 / 5027
    [4]
    The method of claim 3, wherein the flavor adsorbent adsorbent comprises a resin or a mixture of different resins
    [5]
    Method according to claims 1 to 4, wherein the further recovery process comprises washing out the adsorbed volatile flavor components in a volume of water or alcohol to obtain a concentrated fraction of volatile flavor components
    [6]
    The method according to claims 1 to 5, wherein one or more adsorbents, or their composition, are selected based on the flavors to be adsorbed.
    [7]
    The method according to claims 1 to 7 wherein said flavor components are selected from acetaldehyde, N-propanol, ethyl acetate, isobutanol, isoamyl alcohol, isoamyl acetate, ethyl hexanoate, ethyl octanoate.
    [8]
    A method according to claims 1 to 8, wherein the adsorption unit comprises a filled column adsorption.
    [9]
    Use of a fraction comprising volatile flavor components or a concentrated fraction comprising volatile flavor components obtained by a method as indicated in claims 1 to 9 as an ingredient for beer or cider, as a component in beer or cider reconstitution or as a flavor component that can be added to beer or cider.
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    同族专利:
    公开号 | 公开日
    WO2018134285A1|2018-07-26|
    EP3351613A1|2018-07-25|
    BE1025834A1|2019-07-19|
    AR110839A1|2019-05-08|
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    EP3828256A1|2019-11-26|2021-06-02|Clariant ProdukteGmbH|Method for the reduction of aroma loss during the production of ethanol-reduced and ethanol-free beverages|
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    WO2021228871A1|2020-05-15|2021-11-18|Heineken Supply Chain B.V.|Single-serve capsule for preparing alcoholic beer|
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    法律状态:
    2019-08-21| FG| Patent granted|Effective date: 20190814 |
    优先权:
    申请号 | 申请日 | 专利标题
    EP17151916.8A|EP3351613A1|2017-01-18|2017-01-18|Process for the production of beer or cider concentrate|
    EP17151916.8|2017-01-18|
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